Material Safety Data Sheet - RAE Systems

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Material Safety Data Sheet
MSDS Name: Lithium-ion Polymer Battery
Document No: YK.MSDS.2011.108
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: Lithium-ion Polymer Battery
Company Identification: YOKU ENERGY (ZHANGZHOU) CO., LTD.
Address: YOKU Industrial Zone, Nanjing, Zhangzhou, Fujian
Model:426186/2000mAh
Voltage: 7.4V
Energy density:314.329Wh/L
For Emergency: CHEMTREC Day or Night
Domestic North America: 800-424-9300
International Call: 703-527-3887
YOKU ENERGY (ZHANGZHOU) CO., LTD. Call: 0596-7666111
2. COMPOSITION / INFORMATION ON INGREDIENTS
The Lithium-ion battery is hermetically sealed; among its components, the following ones could potentially be
hazardous upon release.
Ingredient Concentration CAS No. EINECS No.
Lithium Cobaltite(LiCoO2) 25~30% 12190-79-3 235-362-0
Graphite Power 10~15% 7440-44-0 231-153-3
Copper Foil 15~20% 7440-50-8 231-259-6
Aluminum Foil 4~6% 7429-90-5 231-072-3
LiPF6 3~5% 21324-40-3 244-334-7
Ethylene glycol carbonate 10~15% 96-49-1 202-510-0
PP or PE 15~20% / /
3. HAZARDS IDENTIFICATION
Classification: Carcinogenic Category 3R40, Xn, sensitizing R43
Most important hazards: There’s limited evidence of a carcinogenic effect. There are possible risks of irreversible
effects. It may cause sensitization by skin contact.
Further information: The sealed lithium-ion battery is not hazardous when used according to recommendations.
Under normal conditions of use, the integrity of the battery’s package and security vent are maintained. The ingredients
are not expected to pose a significant risk to man or the environment. The classification above is based on the contents
being considered as a preparation in accordance with Directive 1999/45/EC.
4. FIRST AID MEASURES
General advice
Show this safety data sheet to the doctor in attendance.
The information below refers to exposure to the ingredients.
Inhalation
Immediate medical attention is required. Move to fresh air. If symptoms persist, call a physician.
Skin contact
Immediate medical attention is required. Wash off immediately with plenty of water for at least 15 minutes. Remove
and wash contaminated clothing before re-use. If skin irritation persists, call a physician.
Eye contact
Immediate medical attention is required. Remove contact lenses. Rinse immediately with plenty of water for at least 15
minutes.
Ingestion
Immediate medical attention is required. Gently wipe or rinse the inside of the mouth with water. Give small amounts
of water to drink. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or
Poison Control Centre immediately.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Foam dry powder, carbon dioxide (CO2), sand.
Extinguishing media which must not be used for safety reasons
Water, water spray
Specific hazards
There’s risk of receptacle bursting.
Special protective equipment for firefighters
In the event of fire, wear self contained breathing apparatus. Wear personal protective equipment.
Hazardous decomposition products
Lithium compounds, carbon oxides, hydrogen fluoride
6. ACCIDENTAL RELEASE MEASURES
The information below refers to exposure to the ingredients.
Personal precautions
Use personal protective equipment. Avoid contact with skin and eyes.
Environmental precautions
Prevent further leakage or spillage if safe to do so.
Do not allow material to contaminate ground water system.
To avoid risks to man and the environment, comply with the instructions for use.
Methods for cleaning up
Pick up and transfer to properly labeled containers. Dispose of in accordance with local regulations.
7. HANDLING AND STORAGE
Handling
Technical measures/Precautions
No special technical protective measures required.
Safe handling advice
Avoid contact with skin and eyes.
Use personal protective equipment.
Follow the instructions for use issued by the producer.
Storage
Technical measures/Storage conditions
Keep in a dry, cool and well-ventilated place, preferably in the temperature range of +5 to +25°C at 65%(+-5%) relative
humidity.
Keep away from heat and sources of ignition.
Keep away from water.
Ensure battery terminals are protected during storage.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational exposure controls
Engineering measures
Ensure adequate ventilation, especially in confined areas.
Personal protective equipment
Not required under normal use.
The information below refers to exposure to the ingredients.
Respiratory protection
Effective dust mask.
Hand protection
Neoprene gloves (EN 374).
Eye protection
Safety glasses with side-shields conforming to EN166
Skin and body protection
Boots, apron, long sleeved clothing.
Hygiene measures
General industrial hygiene practice.
Environmental exposure controls
The information below refers to exposure to the ingredients
Prevent product from entering drains.
Do not allow material to contaminate ground water system.
9. PHYSICAL AND CHEMICAL PROPERTIES
General Information
Form battery (sealed unit) Color: silvery Odor: odorless
Important Health Safety and Environmental Information
Not applicable
10. STABILITY AND REACTIVITY
Stability
Stable under normal conditions.
Hazardous polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Keep away from heat and sources of ignition.
Materials to avoid
Exposure to moisture.
Hazardous decomposition products
Lithium compounds, carbon oxides, hydrogen fluoride
11. TOXICOLOGICAL INFORMATION
The information below refers to exposure to the ingredients.
Local effects
May cause eye/skin irritation. May cause irritation of respiratory tract.
Long term toxicity
No data available. Avoid repeated exposure.
Specific effects
May cause sensitization by inhalation and skin contact. Limited evidence of a carcinogenic effect.
12. ECOLOGICAL INFORMATION
If used as directed and if the integrity of the battery’s package and security vent are maintained, the ingredients are
not expected to pose a significant risk to the environment.
Mobility
No data available.
Persistence and degradability
Not readily biodegradable.
Eco-toxicity effects
No data available.
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products
Dispose of in accordance with local regulations. It must undergo special treatment, e.g. at suitable disposal site, to
comply with local regulations. It should not be released into the environment.
Contaminated packaging
Not applicable.
Further information
Never incinerate Li-Ion batteries.
Never dispose Li-Ion batteries as landfill.
14. TRANSPORT INFORMATION
In airfreight, sealed Lithium-ion batteries are considered as “Lithium Batteries – Not Restricted”, when they can meet
the requirements of PI966 of IATA Dangerous Goods Regulations (UN3481).
In sea-freight, sealed lithium-ion batteries are considered as “Lithium Batteries – Not Restricted”, when they can meet
the requirements of IMDG of IMO Dangerous Goods Regulations (UN3481).
The model is 426186/2000mAh. The voltage is 7.4V. It includes 2 cells in series and in pile. It is 14.8 wh.The battery
doesn’t exceed 100 wh. So this battery doesn’t belong to class 9 with reference to IMDG of IMO, 2011 Dangerous
Goods Regulations, 52nd edition. It complies with the necessary testing requirements under the UN Manual of Tests
and Criteria, Part Ⅲ, sub-section 38.3. It complies with SectionⅡof PI966
For more information, please refer to the newest UN Manual of Tests and Criteria, Part Ⅲ, sub-section 38.3 Lithium
Batteries, IATA Dangerous Goods Regulations, UN Recommendations on the Transport of Dangerous Goods Model
Regulations, International Maritime Dangerous Goods (IMDG) code, Regulations concerning the International
Transport of Dangerous Goods by Rail (RID) and Agreement on Dangerous Goods by Road (ADR). It is especially
important to ensure that batteries are packed in such a way to prevent short circuits.
Reported by:
Company Name:YOKU ENERGY (ZHANGZHOU) CO.,LTD Date: 2011-05-12

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